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Global Harmonized System (GHS)
GHS 84 Hazard Classes
1 Explosives, Unstable Explosive
2 Explosives, Div. 1.1
3 Explosives, Div. 1.2
4 Explosives, Div. 1.3
5 Explosives, Div. 1.4
6 Explosives, Div. 1.5
7 Explosives, Div. 1.6
8 Flammable gases, Category 1
9 Flammable gases, Category 2
10 Flammable gases, Category A
11 Flammable gases, Category B
12 Flammable aerosols, Category 1
13 Flammable aerosols, Category 2
14 Flammable aerosols, Category 3
15 Oxidizing gases, Category 1
16 Gases under pressure, Compressed Gas, Liquefied Gas, Dissolved Gas
17 Gases under pressure, Refrigerated Liquefied Gas
18 Flammable liquids, Category 1
19 Flammable liquids, Category 2
20 Flammable liquids, Category 3
21 Flammable liquids, Category 4
22 Flammable solids, Category 1
23 Flammable solids, Category 2
24 Self-reactive substances and mixtures, Type A
25 Self-reactive substances and mixtures, Type B
26 Self-reactive substances and mixtures, Type C,D
27 Self-reactive substances and mixtures, Type E,F
28 Pyrophoric liquids, Category 1
29 Pyrophoric solids, Category 1
30 Self-heating; substances and mixtures, Category 1
31 Self-heating; substances and mixtures, Category 2
32 Substances and mixtures which in contact with water, emit flammable gases, Category 1
33 Substances and mixtures which in contact with water, emit flammable gases, Category 2
34 Substances and mixtures which in contact with water, emit flammable gases, Category 3
35 Oxidizing liquids; oxidizing solids, Category 1
36 Oxidizing liquids; oxidizing solids, Category 2
37 Oxidizing liquids; oxidizing solids, Category 3
38 Organic peroxides, Type A
39 Organic peroxides, Type B
40 Organic peroxides, Type C, D
41 Organic peroxides, Type E, F
42 Corrosive to metals, Category 1
43 Acute toxicity, oral, Category 1, 2
44 Acute toxicity, oral, Category 3
45 Acute toxicity, oral, Category 4
46 Acute toxicity, oral, Category 5
47 Aspiration hazard, Category 1
48 Aspiration hazard, Category 2
49 Acute toxicity, dermal, Category 1, 2
50 Acute toxicity, dermal, Category 3
51 Acute toxicity, dermal, Category 4
52 Acute toxicity, dermal, Category 5
53 Acute toxicity, inhalation, Category 1, 2
54 Acute toxicity, inhalation, Category 3
55 Acute toxicity, inhalation, Category 4
56 Acute toxicity, inhalation, Category 5
57 Skin corrosion/irritation, Category 1
58 Skin corrosion/irritation, Category 2
59 Skin corrosion/irritation, Category 3
60 Serious eye damage/eye irritation, Category 1
61 Serious eye damage/eye irritation, Category 2/2A
62 Serious eye damage/eye irritation, Category 3
63 Respiratory sensitization, Category 1/1A/1B
64 Skin sensitization, Category 1/1A/1B
65 Germ cell mutagenicity, Category 1A, 1B
66 Germ cell mutagenicity, Category 2
67 Carcinogenicity, Category 1A, 1B
68 Carcinogenicity, Category 2
69 Reproductive toxicity, Category 1A, 1B
70 Reproductive toxicity, Category 2
71 Reproductive toxicity, effects on or via lactation
72 Specific target organ toxicity, single exposure, Category 1
73 Specific target organ toxicity, single exposure, Category 2
74 Specific target organ toxicity, single exposure, Category 3
75 Specific target organ toxicity, repeated exposure, Category 1
76 Specific target organ toxicity, repeated exposure, Category 2
77 Hazardous to the aquatic environment, short term, Acute 1
78 Hazardous to the aquatic environment, short term, Acute 2
79 Hazardous to the aquatic environment, short term, Acute 3
80 Hazardous to the aquatic environment, long term, Chronic 1
81 Hazardous to the aquatic environment, long term, Chronic 2
82 Hazardous to the aquatic environment, long term, Chronic 3
83 Hazardous to the aquatic environment, long term, Chronic 4
84 Hazardous to the ozone layer, Class 1
GHS 9 Pictograms
Exploding Bomb Explosives, Unstable Explosive Explosives, Div. 1.1, 1.2, 1.3, 1.4 Self-reactive Substances and Mixtures, Type A, B Organic Peroxides, Type A, B
Flame Flammable gases, Category 1 Flammable aerosols, Category 1,2 Flammable liquids, categories 1,2,3 Flammable solids, categories 1,2 Self-reactive substances and mixtures, Types B,C,D,E,F Pyrophoric liquids, category 1 Pyrophoric solids, category 1 Self-heating; substances and mixtures, Category 1,2 Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3 Organic peroxides, Types B,C,D,E,F
Flame Over Circle Oxidizing gases, Category 1 Oxidizing liquids; oxidizing solids, Category 1,2,3
Gas Cylinder Gases under pressure, Compressed Gas, Liquefied Gas, Dissolved Gas Gases under pressure, Refrigerated Liquefied Gas
Corrosion Corrosive to metals, Category 1 Skin corrosion/irritation, Category 1 Serious eye damage/eye irritation, Category 1
Skull and Crossbones Acute toxicity, oral, Category 1,2,3 Acute toxicity, dermal, Category 1,2,3 Acute toxicity, inhalation, Category 1,2,3
Exclamation Mark Acute toxicity, oral, Category 4 Acute toxicity, dermal, Category 4 Acute toxicity, inhalation, Category 4 Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2/2A Skin sensitization, Category 1/1A/1B Specific target organ toxicity, single exposure, Category 3 Hazardous to the ozone layer, Class 1
Health Hazard Aspiration hazard, Category 1,2 Respiratory sensitization, Category 1/1A/1B Germ cell mutagenicity, Category 1A, 1B, 2 Carcinogenicity, Category 1A, 1B, 2 Reproductive toxicity, Category 1A, 1B, 2 Specific target organ toxicity, single exposure, Category 1,2 Specific target organ toxicity, repeated exposure, Category 1,2
Environment Hazardous to the aquatic environment, short term, Acute 1 Hazardous to the aquatic environment, long term, Chronic 1,2
91 Hazard Codes and Hazard Statements
H200 Unstable explosive
H201 Explosive; mass explosive hazard
H202 Explosive; severe projection hazard
H203 Explosive; fire, blast or projection hazard
H204 Fire or projection hazard
H205 May mass explode in fire
H220 Extremely flammable gas
H221 Flammable gas
H222 Extremely flammable aerosol
H223 Flammable aerosol
H224 Extremely flammable liquid and vapor
H225 Highly flammable liquid and vapor
H226 Flammable liquid and vapor
H227 Combustible liquid
H228 Flammable solid
H229 Pressurized container
H230 May react explosively even in the absence of air
H231 May react explosively even in the absence of air at elevated pressure and/or temperature
H240 Heating may cause an explosion
H241 Heating may cause a fire or explosion
H242 Heating may cause a fire
H250 Catches fire spontaneously if exposed to air
H251 Self-heating;; may catch fire
H252 Self-heating; in large quantities; may catch fire
H260 In contact with water releases flammable gases which may ignite spontaneously
H261 In contact with water releases flammable gas
H270 May cause or intensify fire; oxidizer
H271 May cause fire or explosion; strong oxidizer
H272 May intensify fire; oxidizer
H280 Contains gas under pressure; may explode if heated
H281 Contains refrigerated gas; may cause cryogenic burns or injury
H290 May be corrosive to metals
H300 Fatal if swallowed
H301 Toxic if swallowed
H302 Harmful if swallowed
H303 May be harmful if swallowed
H304 May be fatal if swallowed and enters airways
H305 May be harmful if swallowed and enters airways
H310 Fatal in contact with skin
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H313 May be harmful in contact with skin
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H320 Causes eye irritation
H330 Fatal if inhaled
H331 Toxic if inhaled
H332 Harmful if inhaled
H333 May be harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H341 Suspected of causing genetic defects
H350 May cause cancer
H351 Suspected of causing cancer
H360 May damage fertility or the unborn child
H361 Suspected of damaging fertility or the unborn child
H362 May cause harm to breast-fed children
H370 Causes damage to organs
H371 May cause damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H410 Very toxic to aquatic life with long-lasting effects
H411 Toxic to aquatic life with long-lasting effects
H412 Harmful to aquatic life with long-lasting effects
H413 May cause long-lasting harmful effects to aquatic life
H420 Harms public health and the environment by destroying ozone in the upper atmosphere
H300+H310 Fatal if swallowed or in contact with skin.
H300+H330 Fatal if swallowed or if inhaled.
H310+H330 Fatal in contact with skin or if inhaled.
H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled.
H301+H311 Toxic if swallowed or in contact with skin.
H311+H331 Toxic in contact with skin or if inhaled.
H301+HH311+H331 Toxic if swallowed, in contact with skin or if inhaled. 82
H302+HH312 Harmful if swallowed or in contact with skin.
H302+H332 Harmful if swallowed or if inhaled
H312+H332 Harmful in contact with skin or if inhaled.
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H303+H313 May be harmful if swallowed or in contact with skin
H303+H333 May be harmful if swallowed or if inhaled
H313+H333 May be harmful in contact with skin or if inhaled.
H303+H313+H333 May be harmful if swallowed, in contact with skin or if inhaled
H315+H320 Cause skin and eye irritation
91 Additional Hazardous Statements
EUH001 Explosive when dry
EUH006 Explosive with or without contact with air
EUH014 React violently with water
EUH018 In use may form flammable/explosive vapor-air mixture
EUH019 May form explosive peroxides
EUH029 Contact with water liberates toxic gas
EUH031 Contact with acids liberates toxic gas
EUH032 Contact with acids liberates very toxic gas
EUH044 Risk of explosion if heated under confinement
EUH059 Hazardous to the ozone layer
EUH066 Repeated explosion may cause skin dryness or cracking
EUH070 Toxic by eye contact
EUH071 Corrosive to the respiratory tract
EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH201A Warning! Contains lead.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203 Contains chromium (VI). May produce an allergic reaction.
EUH204 Contains isocyanates. May produce an allergic reaction.
EUH205 Contains epoxy constituents. May produce an allergic reaction.
EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207 Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.
EUH208 Contains &ltname of sensitizing substance&gt. May produce an allergic reaction.
EUH209 Can become highly flammable in use.
EUH209A Can become flammable in use.
EUH210 Safety data sheet available on request.
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.
128 Precautionary Codes and Precautionary Statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/.../combustible materials.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230 Keep wetted with...
P231 Handle under inert gas.
P232 Protect from moisture.
P233 Keep container tightly closed.
P234 Keep only in original container.
P235 Keep cool.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P244 Keep reduction valves free from grease and oil.
P250 Do not subject to grinding/shock/.../friction.
P251 Pressurized container
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P263 Avoid contact during pregnancy/while nursing.
P264 Wash skin thoroughly after handling.
P270 Do no eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P282 Wear cold insulating gloves/face shield/eye protection.
P283 Wear fire/flame resistant/retardant clothing.
P284 Wear respiratory protection.
P231 + P232 Handle under inert gas. Protect from moisture.
P301 IF SWALLOWED
P302 IF ON SKIN
P303 IF ON SKIN (or hair)
P304 IF INHALED
P305 IF IN EYES
P306 IF ON CLOTHING
P308 IF exposed or concerned
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P313 Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P315 Get immediate medical advice/attention.
P320 Specific treatment is urgent (see label).
P321 Specific treatment (see label).
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332 If skin irritation occurs
P333 If skin irritation or rash occurs
P334 Immerse in cool water/wrap in wet bandages.
P335 Brush off loose particles from skin.
P336 Thaw frosted parts with lukewarm water. Do not rub affected area.
P337 If eye irritation persists
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 If experiencing respiratory symptoms
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P353 Rinse skin with water/shower.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P364 And wash it before reuse.
P370 In case of fire
P371 In case of major fire and large quantities
P372 Explosion risk in case of fire.
P373 DO NOT fight fire when fire reaches explosives.
P375 Fight fire remotely due to the risk of explosion.
P376 Stop leak if safe to do so.
P377 Leaking gas fire
P378 Use for extinction
P380 Evacuate area.
P381 Eliminate all ignition sources if safe to do so.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P306 + P360 IF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P308 + P311 IF exposed: Call a POISON CENTER or doctor/physician.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P332 + P313 If skin irritation occurs
P333 + P313 If skin irritation or rash occurs
P336 + P315 Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.
P337 + P313 If eye irritation persists
P342 + P311 If experiencing respiratory symptoms
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370 + P376 In case of fire: Stop leak if safe to do so.
P370 + P378 In case of fire: Use for extinction.
P301 +P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334+P335 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
P370+P372+P380+P373 In case of fire
P370+P380+P375+P378 In case of fire
P401 Store in accordance with…
P402 Store in a dry place.
P403 Store in a well-ventilated place.
P404 Store in a closed container.
P405 Store locked up.
P406 Store in corrosive resistant/... container with a resistant inner liner.
P407 Maintain air gap between stacks/pallets.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding ... °C/ ...°F.
P412 Do not expose to temperatures exceeding 50°C/ 122°F.
P413 Store bulk masses greater than ... kg/ ... lbs at temperatures not exceeding ... °C/ ... °F.
P420 Store away from other materials.
P402 + P404 Store in a dry place. Store in a closed container.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P410 + P412 Protect from sunlight. Do no expose to temperatures exceeding 50 Celsius Degrees.
P501 Dispose of contents/ container to an approved waste disposal plant.
P502 Refer to manufacturer o supplier for information on recovery or recycling.